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Diesel Exhaust Fluid

DEF (Diesel Exhaust Fluid) is a non-toxic, colorless, odorless, and non-flammable fluid used in diesel engines to reduce harmful emissions.

Tata def

🔹 What is DEF made of?

DEF is a mixture of 32.5% urea (a nitrogen compound) and 67.5% deionized water.


🔹 Why is DEF used?

DEF is used in vehicles with SCR (Selective Catalytic Reduction) technology. Its main purpose is to:

Reduce NOx (Nitrogen Oxide) emissions,
✅ Help diesel engines meet Bharat Stage (BS) VI / Euro 6 / EPA emission standards,
✅ Improve overall air quality.


🔹 How does it work?

  1. Injection: DEF is injected into the exhaust stream, not the fuel system.
  2. Reaction: In the hot exhaust, DEF breaks down into ammonia (NH₃).
  3. Conversion: Ammonia reacts with NOx in the SCR catalyst, converting them into:
    • Nitrogen (N₂) — harmless and 78% of air
    • Water vapor (H₂O)

👉 NOx + NH₃ → N₂ + H₂O


🔹 Where is DEF stored?

It is stored in a separate DEF tank in the vehicle (usually has a blue cap). It's not mixed with diesel fuel.


🔹 Important Points

  • DEF freezes at -11°C, so DEF tanks may be heated.
  • Shelf life: ~1 year if stored properly.
  • Consumed at ~3–5% of diesel usage. (e.g., 1L DEF per 20L diesel)
  • Running out of DEF: Engine may reduce power or not start until refilled.

🔹 In India

With the introduction of Bharat Stage VI (BS6) norms in 2020, many trucks, buses, and SUVs with large diesel engines started using DEF with SCR systems.


How does SCR system work?

The SCR (Selective Catalytic Reduction) system is an advanced emission control technology used in diesel vehicles to reduce nitrogen oxides (NOx) — one of the most harmful pollutants emitted by diesel engines.


How SCR System Works – Step-by-Step

🔹 1. Diesel Engine Produces NOx

  • After combustion, diesel engines release hot exhaust gases that contain:
    • NOx (Nitrogen Oxides)
    • CO₂
    • Particulate Matter (PM)

🔹 2. DEF (Diesel Exhaust Fluid) is Injected

  • A small amount of DEF (32.5% urea + 67.5% deionized water) is injected into the exhaust stream, after the turbocharger and DPF, but before the SCR catalyst.

🔹 3. DEF Converts to Ammonia

  • In the hot exhaust:
    (NH₂)₂CO + H₂O → 2 NH₃ + CO₂
    
  • The urea in DEF decomposes into ammonia (NH₃) and carbon dioxide (CO₂).

🔹 4. Ammonia Reacts with NOx in SCR Catalyst

  • Inside the SCR catalyst, ammonia reacts with NOx:
    4 NO + 4 NH₃ + O₂ → 4 N₂ + 6 H₂O
    6 NO₂ + 8 NH₃ → 7 N₂ + 12 H₂O
    
  • This converts toxic NOx into:
    • Nitrogen gas (N₂) — harmless and already in the air
    • Water vapor (H₂O) — harmless

🔹 5. Clean Gases Exit Through the Tailpipe

  • Final emission is mostly:
    • Nitrogen
    • Water vapor
    • Very low CO₂
  • Meets BS6 / Euro 6 / EPA standards

🔧 Main Components of an SCR System:

Component Function
DEF Tank Stores Diesel Exhaust Fluid
DEF Injector Sprays DEF into the exhaust
Mixer Ensures proper mixing of DEF and exhaust gas
SCR Catalyst Site of chemical reaction (NOx → N₂ + H₂O)
ECU (Engine Control Unit) Controls DEF injection and monitors sensors
NOx Sensors Measure NOx levels before & after SCR

📌 Benefits of SCR:

  • ✅ Reduces NOx by up to 90%
  • ✅ Improves fuel efficiency
  • ✅ Lowers environmental pollution
  • ✅ Complies with stringent emission norms

What is and why deionised water

Deionised Water (also spelled deionized water or DI water) is water that has had most or all of its mineral ions removed, such as:

  • Calcium (Ca²⁺)
  • Magnesium (Mg²⁺)
  • Sodium (Na⁺)
  • Chloride (Cl⁻)
  • Sulfate (SO₄²⁻)
  • Iron (Fe²⁺ / Fe³⁺)
  • Other dissolved salts

🔹 How is deionised water made?

It is made by passing water through ion exchange resins that remove positively charged (cation) and negatively charged (anion) ions.

There are two key types of resins:

  • Cation resin removes positive ions (like Ca²⁺, Na⁺)
  • Anion resin removes negative ions (like Cl⁻, SO₄²⁻)

🔹 What’s the difference between types of water?

Type of Water Description Contains Ions?
Tap Water Regular water with minerals ✅ Yes
Distilled Water Steam-condensed water (some ions remain) ⚠️ Few ions
Deionised Water Chemically treated to remove all ions ❌ No
RO Water Filtered through reverse osmosis membrane ⚠️ Very low

🔹 Why is deionised water used?

Because it's pure and non-reactive, it's used in:

  • Laboratories
  • Pharmaceuticals
  • Electronics and battery industries
  • Automotive: e.g. in Diesel Exhaust Fluid (DEF) to avoid contaminating the SCR system

How is D.E.F used?

DEF

DEF (Diesel Exhaust Fluid) is used only in diesel vehicles that have Selective Catalytic Reduction (SCR) systems to reduce harmful NOx emissions.

Here’s a simple step-by-step explanation of how DEF is used:


🔷 1. DEF is stored in a separate tank

  • Your vehicle will have a DEF tank with a blue cap (not to be confused with the diesel fuel tank).
  • It is not mixed with diesel.
  • Capacity depends on vehicle type.

🔷 2. DEF is automatically injected into the exhaust system

  • After the engine burns diesel, hot exhaust gases containing Nitrogen Oxides (NOx) are produced.
  • Just before the exhaust gases enter the SCR catalyst, a small, controlled amount of DEF is injected into the exhaust pipe (not the engine).

🔷 3. DEF reacts to form ammonia

  • DEF breaks down due to heat into:
    • Ammonia (NH₃)
    • Carbon dioxide (CO₂)
  • The chemical reaction:
    (NH₂)₂CO + H₂O → NH₃ + CO₂

🔷 4. Ammonia converts NOx into harmless gases

  • Inside the SCR Catalyst, ammonia reacts with NOx: 4NO + 4NH₃ + O₂ → 4N₂ + 6H₂O

This reaction converts toxic NOx into: ✅ Nitrogen (N₂) – safe and already in the air
Water vapor (H₂O) – harmless


🔷 5. Result: Cleaner emissions

  • This system drastically reduces air pollution, helping vehicles meet emission norms like:
    • BS-VI (India)
    • Euro 6 (Europe)
    • EPA Tier 2/3 (USA)

🔷 6. What happens if DEF runs out?

  • The vehicle will usually:
    • Give a warning alert
    • Limit engine power or speed
    • Not start until DEF is refilled (in many vehicles)

👉 This is done to force compliance with emission laws.


🔷 7. How often is DEF needed?

  • DEF consumption is usually: 🔸 3–5% of diesel use
    • E.g., if you burn 100 L of diesel, you’ll use 3–5 L of DEF.
  • You refill DEF just like you refuel diesel, usually every few thousand kilometers.

DEF (Diesel Exhaust Fluid) is injected after the exhaust valve, but before or inside the silencer (muffler) section — specifically into the exhaust stream just before the SCR catalyst, which is usually part of or located near the silencer in modern diesel vehicles.


🔹 Exact Location:

  1. Exhaust Valve → Hot exhaust gases (with NOx) exit the engine.
  2. Exhaust Pipe → Gases flow through the pipe.
  3. DEF Injector sprays DEF into this hot exhaust stream.
  4. SCR Catalyst → Here, DEF turns into ammonia (NH₃) and reduces NOx to N₂ + H₂O.
  5. Silencer/Muffler (sometimes combined with the SCR system) → Quietens the sound and releases cleaned gases.

So, DEF is not injected into the engine or silencer directly. It’s injected into the exhaust pipe upstream of the SCR, typically located before or as part of the silencer unit.

TATA D.E.F

TATA D.E.F stands for Tata Diesel Exhaust Fluid, a branded version of Diesel Exhaust Fluid manufactured or supplied by Tata Motors (or its authorized partners) for use in Tata's BS6 diesel vehicles equipped with SCR (Selective Catalytic Reduction) systems.


🔹 Key Features of TATA D.E.F:

  1. Meets ISO 22241 and BS6 emission standards
  2. ✅ Specifically designed for Tata commercial and passenger diesel vehicles
  3. ✅ Supplied in safe, sealed containers (10L, 20L, 210L drums, etc.)
  4. ✅ Non-toxic, non-flammable, colorless liquid (32.5% urea + 67.5% deionized water)
  5. ✅ Works with the SCR system to reduce NOx emissions
  6. ✅ Extends the life of SCR components when used properly

🔹 Why use Tata D.E.F?

  • Ensures vehicle warranty compliance
  • Prevents damage to the SCR system (wrong fluid can block injectors or corrode parts)
  • Improves fuel efficiency and lowers emission penalties

🔹 Where to buy TATA D.E.F?

  • Tata Motors authorized service centers
  • Select petrol pumps and truck stops
  • Genuine auto part shops (look for "ISO 22241-compliant DEF")

⚠️ Never use water, fake DEF, or urea fertilizers — this will damage your emission system and void warranty.

Other DEF vendors 

Apart from TATA, many authorized vendors and manufacturers produce and sell Diesel Exhaust Fluid (DEF) under various brand names. These companies follow the ISO 22241 standard to ensure safe and effective performance in SCR-equipped diesel vehicles.


Popular DEF Brands in India & Globally

🔷 India-Based Brands:

  1. IndianOil (Servo DEF)

    • Branded as Servo DEF or Servo Greenmile
    • Available at many fuel stations and OEM partners
  2. HPCL (HP AdBlue)

    • Sold as HP BlueSky DEF
    • Available at HP petrol pumps and service centers
  3. Bharat Petroleum (BPCL)

    • Sold as MAK AdBlue
    • Widely available for BS6 trucks and buses
  4. Tata Motors (TATA DEF)

    • Branded for Tata commercial and passenger diesel vehicles
  5. Ashok Leyland DEF

    • Available through their own service network
  6. Mahindra DEF

    • Supplied through Mahindra Truck & Bus service points
  7. Greenchem / EcoDEF / DEFtech

    • Independent Indian DEF manufacturers and suppliers

🔷 International & Global Brands (Also available in India):

  1. Shell DEF
  2. TotalEnergies AdBlue
  3. Bosch DEF
  4. Yara Air1 AdBlue – One of the largest global suppliers
  5. BlueDEF (by Old World Industries) – Widely used in North America

📌 How to choose the right DEF?

Always ensure:

  • ✅ The label says "ISO 22241 Compliant"
  • ✅ It’s clear, colorless, odorless liquid
  • ❌ Avoid fertilizers or fake products (they can damage the SCR system)

Advantages and disadvantages of D.E.F

Here’s a clear and balanced overview of the advantages and disadvantages of Diesel Exhaust Fluid (DEF):


Advantages of DEF

1. Reduces Air Pollution

  • DEF drastically reduces NOx (Nitrogen Oxide) emissions by up to 90%, which are harmful pollutants contributing to smog, acid rain, and respiratory issues.

2. Enables Compliance with Emission Norms

  • DEF allows vehicles to meet strict emission standards like:
    • BS6 (India)
    • Euro 6 (Europe)
    • EPA Tier 2/3 (USA)

3. Improves Engine Efficiency

  • Engines with SCR systems (which use DEF) can be tuned for better fuel efficiency, as they don’t rely on internal EGR (Exhaust Gas Recirculation) alone.

4. Environmentally Friendly

  • Converts harmful gases into harmless nitrogen (N₂) and water vapor.

5. Non-toxic and Safe

  • DEF is non-flammable, non-explosive, and harmless to handle (though not for drinking!).

Disadvantages of DEF

1. Additional Maintenance

  • DEF systems add extra components (tank, injectors, SCR unit) that require maintenance and care.

2. Extra Operating Cost

  • Regular purchase and refilling of DEF adds to the running cost, especially for commercial vehicles.

3. Freezing and Storage Issues

  • DEF freezes at -11°C, so vehicles in colder climates may need heated tanks or lines.
  • It also degrades in heat and sunlight if not stored properly.

4. If DEF Runs Out – Vehicle May Not Start

  • Most vehicles with SCR will limit performance or not start if DEF is missing, even if diesel is full.

5. Fake/Low-Quality DEF Can Damage the System

  • Using non-ISO 22241-compliant or adulterated DEF can clog injectors or corrode the SCR catalyst, leading to high repair costs.

⚖️ Conclusion

DEF is a great solution for cleaner air, but...
✔ It helps the environment and improves fuel efficiency
✖ But it requires careful maintenance and pure quality use

Is DEF flammable?

No, Diesel Exhaust Fluid (DEF) is not flammable.


🔹 Why is DEF not flammable?

  • DEF is made of 32.5% urea and 67.5% deionized water.
  • It contains no hydrocarbon or fuel content.
  • It does not catch fire or support combustion, even when exposed to high temperatures.

🔥 Fire Safety of DEF:

Property Status
Flash point ❌ None (no ignition point)
Flammable ❌ No
Explosive ❌ No
Toxic when burned ⚠️ Can emit ammonia vapors if overheated, but not flammable

✅ Safety Tips:

  • Store in a cool, dry place away from direct sunlight.
  • If spilled, just wash with water — it's safe.
  • Avoid mixing it with fuel or chemicals.

So yes, DEF is completely safe to store and handle, even around heat or flame sources.

What's the cost of D.E.F. per litre

In India, Diesel Exhaust Fluid (DEF/AdBlue) typically costs ₹30–₹65 per litre depending on the brand, packaging, and quantity. Here’s a clearer breakdown:


💧 Retail Pricing (Small Packs: 5–20 L)

HP DEF (20 L bucket): ₹64.9 per litre  

Tata Genuine DEF (20 L): ₹55 per litre on Amazon (20 L pack ₹1,100)  

Amazon retail (5 L pack): ≈₹160 per litre (₹799 for 5 L)  

📦 Wholesale/Bulk Pricing

OEMNXT / generic brands: ₹30–₹40 per litre in drums (210 L, 1000 L)  

Trade suppliers: ₹34–₹40 per litre in large quantities  

🛠️ Why Prices Vary

  • Smaller packaging has higher per-litre cost due to packaging and logistics.
  • Bulk orders save money but you need proper storage (cool, away from sunlight).
  • Prices rise slightly with ISO 22241 certification and brand reputation.

Summary Table

Purchase Type Price Range (₹/L)
Small retail pack ₹55–₹65
Bulk drums (210 L) ₹30–₹40
Online 5 L packs ₹160 (retail premium)

🛒 Recommended Buy Strategy

  • Personal/occasional use (cars, small SUVs): Go with 5–20 L branded packs (Tata, HP).
  • Commercial/fleet use: Opt for bulk drums or IBCs to cut costs, but ensure proper storage and certification.

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